Попробуйте, кроме ошибки декодирования JSON

try:
    qByUser = byUsrUrlObj.read()
    qUserData = json.loads(qByUser).decode('utf-8')
    questionSubjs = qUserData["all"]["questions"]
except ValueError:  # includes simplejson.decoder.JSONDecodeError
    print('Decoding JSON has failed')
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